Solid wastes - sources - sludge from industry and farm wastes –Characteristics - Environmental problems
11Solid wastes - sources - sludge from industry and farm
wastes –Characteristics - Environmental problems
Solid wastes-Sources
1. Residential sources
Garbage from residential places include food wastes, plastics, paper,
glass, leather, cardboard, metals, yard wastes, ashes and special wastes like
bulky household items (electronics, tires, batteries, old mattresses and used
oil). Most homes have garbage bins where they can throw away their solid wastes
in and later the bin is emptied by a garbage collecting firm or person for
treatment.
2. Industrial sources
Industrial waste is waste produced by industrial
activity, such as that of factories, mills and mines. Major industries that are producing waste are leather industries, Sugar and distilleries industries, Paper industries
and textile mill. Most industrial waste is neither hazardous nor toxic, but the quantity produced is large. It has serious
environmental impact as of air
pollution, water pollution and soil pollution eg. Pressmud from sugar industry,
spent wash and yeast sludge from distillery industry, paper sludge, fly ah from paper industry etc.,
3. Commercial
Commercial facilities and buildings are yet another source of solid
waste today. Commercial buildings and facilities in this case refer to hotels,
markets, restaurants, go downs, stores and office buildings. Some of the solid
wastes generated from these places include plastics, food wastes, metals,
paper, glass, wood, cardboard materials, special wastes and other hazardous
wastes.
4. Institutional
The institutional centers like schools, colleges, prisons, military
barracks and other government centers also produce solid waste. Some of the
common solid wastes obtained from these places include glass, rubber waste,
plastics, food wastes, wood, paper, metals, cardboard materials, electronics as
well as various hazardous wastes.
5. Construction demolition areas
Construction sites and demolition sites also contribute to the solid
waste problem. Construction sites include new construction sites for buildings
and roads, road repair sites, building renovation sites and building demolition
sites. Some of the solid wastes produced in these places include steel
materials, concrete, wood, plastics, rubber, copper wires, dirt and glass.
6. Municipal services
The urban centers also contribute immensely to the solid waste crisis in
most countries today. Some of the solid waste brought about by the municipal
services include, street cleaning, wastes from parks and beaches, wastewater
treatment plants, landscaping wastes and wastes from recreational areas
including sludge
7. Treatment plants and sites
Heavy and light manufacturing plants also produce solid waste. They
include refineries, power plants, processing plants, mineral extraction plants
and chemicals plants. Among the wastes produced by these plants include,
industrial process wastes, unwanted specification products, plastics, metal
parts just to mention but a few.
8. Agricultural
Crop farms, orchards, dairies, vineyards and feedlots are also sources
of solid wastes. Agricultural wastes also include spoiled food, pesticide
containers and other hazardous materials.
9. Biomedical
This refers to hospitals and biomedical equipment and chemical
manufacturing firms. In hospitals there are different types of solid wastes
produced. Some of these solid wastes include syringes, bandages, used gloves,
drugs, paper, plastics, food wastes and chemicals. All these require
proper disposal or else they will cause a huge problem to the
environment and the people in these facilities.
Sludge
from industries
Sludge refers to the residual, semi-solid material left from industrial wastewater, or sewage treatment processes. Industrial
wastewater solids are also referred to as sludge, whether generated from
biological or physical-chemical processes. Surface water plants also generate
sludge made up of solids removed from the raw water.
In Tamil Nadu alone, the ETPs generate
about 100 tonnes of tannery sludge per day (dry basis). As the sludge contains relatively
higher concentration of chromium, it is classified as hazardous material. Tannery industrial
sludge is alkaline in nature (pH 7.5 to 10). Tannery industrial sludge are rich
in N, especially organic N, but very poor in P. Tannery sludge contain sulfide,
which impart high antibacterial activity along with chromium and organic
compounds.
The average concentrations of Cr in the tannery sludge
is 10,000 mg/kg followed by Na (6070 mg/kg). In addition to Cr and Na other
heavy metals like Zn, Cu, Mg, Cd, Pb and As are also present. In general the
metal ions present in the sludge followed the order of Cr > Na > Ca > Mg >Cu >Zn> Pb > As > Cd.
Environmental effect by tannery waste was
that the most environmental effect was bad smell to the surrounding area and
the secondly scarcity of fresh water. About 40 heavy metal and acid are used in
the processing of raw hides. Due to lack of proper management facilities the
tannery waste create environmental pollution day by day. Pollution of
environment is one of the most horrible ecological crisis to which we are
subjected today. About 95% of the tannery industries have been built in
unplanned way at the congested places during the last fifty years. These
unplanned tanneries caused environmental pollution very much. It was showed
that the most harmful environmental effect was bad smell to the surrounding
areas which caused environmental pollution. It caused skin diseases by spreading
of waste in water and soil. Workers in the tanneries suffer from
gastrointestinal, dermatological, and other diseases, and 90% of this population
dies before the age of 50. The presence of arsenic in the ground water increasing
scarcity of fresh drinking water which causes skin lesion, kidney, liver
complication, cancer etc.
The paper mill sludge produced by the paper
industries are wet, sticky and had a strong odour. The moisture content in the
sludge ranged from 45%–78% with an average of 65.08%. The composting of paper
mill is recognized as the most adequate pre-treatment in order to obtain a
material which may respond more efficiently with reduced odour and can help
sanitize the material. The sludge
contains CaCO3 that could be helpful for the acid soil improvement
by neutralizing the soil acidity. Due to the cellulosic fiber content application
of sludge can hold moisture in the soil system. The electrical conductivity
values of the six paper mill sludge ranged from 0.51–3.08 mS·cm−1. This
indicates that continuous application of sludge will increase soil
salinity
Paper mill sludge is usually disposed of in
landfills. The total metal concentration is a poor indicator of metal
bioavailability, mobility or toxicity, because these properties are strongly
dependent on the chemical association of the individual components of the
sample. Natural and anthropogenic environmental changes greatly influence the
behaviour of metallic pollutants in sludge, as the form in which they occur may
be change. Such external factors can include pH, temperature, the redox
potential, organic matter decomposition, leaching, ion exchange processes and
microbiological activity. In landfills, the pH may change due to the natural
formation of acids during anaerobic microbiological degradation.
Micro-organisms can alter the mobility of metals through reduction,
accumulation, mobilization, and immobilization. During the re-use and long-term
storage of wastes, acidification may be caused by sulfide oxidation, the
buffering capacity of natural waters, acidic rainwater and atmospheric CO2.
If heavy metals are present in sludge in the loosely bound fraction, such as
soluble, exchangeable and adsorbed forms, they tend to be mobilized.
The Ca and Mg
contents ranged from 0.36%–1.28% and 0.41%–1.06%, respectively.
In the paper mill
sludge, Na content ranged from 0.64% to 0.88%. Sodium is used in the pulping
process as sodium hydroxide and Al is associated with the use of clays in the
paper making process and the use of Al salts (e.g., aluminum sulfate) in the
wastewater treatment process.
Total
concentrations of heavy metals and micro-nutrients were high in the paper mills with the
exception of Cr.
High concentrations of nitrogen, phenol, chloride
and heavy metals were detected in distillery sludge. If it is disposed in the
soil without any treatment it will affect the soil properties by clogging soil
micro-pores, decreasing soil microbial diversity.
Agricultural waste
Agricultural waste also called Green waste
is biodegradable waste that
can be composed of garden or park waste, such as grass or flower cuttings
and hedge trimmings, as well as
domestic and commercial food waste and animal waste. The differentiation green identifies
it as high in nitrogen, as opposed
to brown waste, which is
primarily carbonaceous.
The constituents of animal biosolids typically contain
·
Strong organic content —
much stronger than human sewage
·
High solids concentration
·
High nitrate and
phosphorus content
·
Antibiotics
·
Synthetic hormones
Animal wastes from cattle can be
produced as solid or semisolid manure or as a liquid slurry. The
production of slurry is especially common in housed dairy cattle
Piggery waste
Piggery waste is comparable to other animal wastes and is
processed as for general animal waste, except that many piggery wastes contain
elevated levels of copper that
can be toxic in the natural environment. The liquid fraction of the waste is
frequently separated off and re-used in the piggery to avoid the prohibitively
expensive costs of disposing of copper-rich liquid. Ascarid worms and their eggs are also common in piggery waste and can
infect humans if wastewater treatment is ineffective.
Poultry waste
The production of poultry results in: hatchery
wastes, manure (bird excrement), litter (bedding materials such as sawdust,
wood shavings, straw and peanut or rice hulls), and on-farm mortalities. The
processing of poultry results in additional waste materials, including offal
(feathers, entrails and organs of slaughtered birds), processing wastewater and
biosolids. Most of these by-products can provide organic and inorganic
nutrients that are of value if managed and recycled properly, regardless of
flock size. However, they also give rise to potential environmental and human
health concerns as the sources of elements, compounds (including veterinary
pharmaceuticals), vectors for insects and vermin, and pathogenic
microorganisms. Specific concerns that are well documented include degradation
of nearby surface and/or groundwater, resulting from increased loading of
nutrients such as nitrogen and phosphorus (and potassium in some locations).
Air quality issues include the fate and effect of ammonia, hydrogen sulphide,
volatile organic compounds (VOCs) and dust particulates emitted from poultry
production facilities.


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